Rav Elazar Stern, a posek on the Badatz of Kehilos, has paskened that while one should try to get such a product with a KLP hechsher, one could wash his hands with any of these products if unable to get the KLP version, despite the possibility of the alcohol ingredient being made from chametz. If one uses an uncertified product on pesach, before touching food he should wash his hands well to ensure all remnants of the alcogell will have been washed away.
source: Kikar
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COR has come out with the same ruling. They have confirmed that Purell is chametz free.
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